Shijiazhuang Hongtai Rubber Co., Ltd.

  • Name: HT206 MSDS
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MATERIAL SAFETY DATA SHEET

FILE NO.:

HT 206

 

MSDS DATE: 1/1/2015

 

 

SECTION 1: PRODUCT AND COMPANY IDENTIFICATION

 

 

 

 

PRODUCT NAME:

HT206

 

PRODUCT CODES:

206

 

 

 

MANUFACTURER: SHIJIAZHUANG HONGTAI RUBBER CO LTD

 

NO 1, Fanjiazhuang Industry Zone

 

Xinji, Shijiazhuang, Hebei, China 052360

 

 

EMERGENCY PHONE:

 

 

OTHER CALLS:    +86 311-8327 3001  (China)

 

 

 

 

FAX PHONE:          +86 311-8327 6008 (China)

 

 

 

 

CHEMICAL FAMILY:Carboxylated Butadiene Acrylonitrile Polymer

 

 

PRODUCT USE:     Raw material for industrial use

 

PREPARED BY:

 

 

SECTION 1 NOTES:

 

 

 

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

 

INGREDIENT:

 

 

CAS NO.

Chemical Name

% WT

Proprietary

Carboxylated Butadiene Acrylonitrile Polymer

40-50

Proprietary

Stabilizer

1-5

7664-41-7

Ammonia

0.35(Max)

 

PAGE 1 OF 10

 


MATERIAL SAFETY DATA SHEET

FILE NO.:

HT 206

 

MSDS DATE: 1/1/2015

107-13-1

Acylonitrile

40ppm (Max)

7732-18-5

Water

45-60

 

 

Other Information: The product contains, as generally common for products of this kind, traces of monomers due to the manufacturingprocess, even after intensive cleaning

 

SECTION 2 NOTES:

 

SECTION 3: HAZARDS IDENTIFICATION

 

EMERGENCY OVERVIEW: No significant immediate hazards for emergency response are known.

 

 

 

 

POTENTIAL HEALTH EFFECTS

 

 

EYES: Direct contact with this material may cause eye irritation including tearing and redness. Corneal injury is unlikely.

 

 

SKIN: Short single exposure not likely to cause significant skin irritation. Prolonged and repeated exposure may cause slight skin irritation.Material may stick to skin causing irritation upon removal. A single, prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts.

 

INGESTION: Single dose oral toxicity is considered to be extremely low. Ingestion (swallowing) may irritate the mouth, throat, and stomach.No hazards anticipated from swallowing small amounts incidental to normal handling operations.

 

INHALATION: Inhalation of vapor may cause irritation to the respiratory tract (nose, throat, and lungs). With good ventilation, single exposureto vapors is not likely to be hazardous.

 

Carcinogenic Effects

 

This material contains acrylonitrile monomer which is listed by the International Agency for Research on Cancer (IARC) as a group 2B cancer causing agent (possibly carcinogenic to humans). The National Toxicology Program (NTP) has listed acrylonitrile as a substance that may reasonably be anticipated to be a human carcinogen.

 

 

 

 

 

 

 

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MATERIAL SAFETY DATA SHEET                                                                       FILE NO.:

 

HT 206                                                                                                                                                MSDS DATE: 1/1/2015

 

 

SECTION 3 NOTES:

 

SECTION 4: FIRST AID MEASURES__________________________________________________________________________________

 

 

Eye Contact

 

Immediately flush eyes with large quantities of clean water for at least 15 minutes. Consult a physician.

 

 

Skin Contact

 

Wash skin with soap and water. Remove contaminated clothing. Seek medical attention if irritation develops. Wash contaminated clothing before reuse.

 

Inhalation

 

Remove affected individual(s) to fresh air. Seek medical attention if breathing difficulty develops.

 

 

Ingestion

 

If swallowed, seek medical attention. Do not induce vomiting unless directed to do so by medical personnel.

 

 

Notes to Physician

 

No specific antidote. Supportive care. Treatment based on judgement of the physician in response to reactions of the patient.

 

 

SECTION 4 NOTES:

 

 

 

SECTION 5: FIRE-FIGHTING MEASURES

 

Properties

 

Flash Point: Not applicable.

 

Method Used: Not applicable.

 

Autoignition Temperature: Not applicable.

 

Flammable Limits in Air (Lower): Not applicable.

 

Flammable Limits in Air (Upper): Not applicable

 

 

Fire Fighting Extinguishing Media

 

To extinguish combustible residues of this product, use water fog, carbon dioxide, dry chemical or foam.

 

PAGE 3 OF 10


MATERIAL SAFETY DATA SHEET                                                                       FILE NO.:

 

HT 206                                                                                                                                                MSDS DATE: 1/1/2015

 

 

Fire Fighting Equipment

 

Wear self-contained breathing apparatus (SCBA) and full fire-fighting protective clothing. If protective equipment is not available or not used, fight fire from a protected location or safe distance.

 

Fire Fighting Instructions

 

Keep people away. Isolate fire area and deny unnecessary entry. Containers of this material may build up pressure if exposed to heat (fire). Use a water spray to cool fire-exposed containers.

 

Fire / Explosion Hazards

 

This material will not burn unless it is evaporated to dryness.

 

 

Hazardous Combustion Products

 

Under fire conditions, some components of this product may decompose. The smoke may contain unidentified toxic and/or irritating compounds. Hazardous combustion products may include and are not limited to hydrocarbons, carbon monoxide and dense smoke.

 

SECTION 5 NOTES:

 

 

 

SECTION 6: ACCIDENTAL RELEASE MEASURES

 

ACCIDENTAL RELEASE MEASURES:

 

 

Personal Precautions

 

Avoid unnecessary exposure and contact. Barricade the area to restrict access. Persons not wearing protective equipment (see Section 8) should be excluded from the area of the spill until clean-up has been completed.

 

Environmental Precautions

 

Stop leak at source when it is safe to do so. Dike and contain spill. Prevent spilled material from contaminating soil or entering drains, sewers, streams or other bodies of water.

 

Cleanup Procedures

 

Avoid dilution with water to minimize the extent of the spill. Recover and recycle spilled latex if possible, otherwise, collect with absorbent material and transfer to appropriate containers for disposal. Water may be used for final cleaning of affected area.

 

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MATERIAL SAFETY DATA SHEET                                                                       FILE NO.:

 

HT 206                                                                                                                                                MSDS DATE: 1/1/2015

 

 

SECTION 6 NOTES:

 

 

 

SECTION 7: HANDLING AND STORAGE

 

HANDLING AND STORAGE:

 

 

Handling Information

 

Practice reasonable care to avoid repeated, prolonged skin contact. An eye wash station and a safety shower should be readily accessible to workers wherever this material is stored or used.

 

Storage Information

 

Keep from freezing. Store at temperatures between 41° F and 104° F. Material may develop bacteria odor on long-term storage. No safety problems known.

 

SECTION 7 NOTES:

 

 

 

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

 

Exposure Limits Guidelines

 

There are no exposure limits assigned to the polymer in this product by the Occupational Safety and Health Administration (OSHA) or American Conference of Governmental Industrial Hygenists (ACGIH).

 

The Occupational Safety and Health Administration (OSHA) Permissible Exposure Limit (PEL) for ammonia is 50 ppm for an 8-hour Time Weighted Average (TWA). The American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV) for ammonia is 25 ppm for an 8-hour Time Weighted Average (TWA) and Short Term Exposure Level of 35 ppm.

 

The Occupational Safety and Health Administration (OSHA), has established a Permissible Exposure Limit (PEL) of 2 ppm and an action level of 1ppm for acrylonitrile. Refer to 29 CFR 1910.1045 for for information. The American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV) for acrylonitrile is 2 ppm, Time Weighted Average (TWA) for an 8-hour workday and a 40-hour work week with a skin notation which indicates absorption through the skin could add to the employees exposure.

 

Engineering Controls

                                                                                                                                                          PAGE 5 OF 10

MATERIAL SAFETY DATA SHEET                                                                       FILE NO.:

 

HT206                                                                                                       MSDS DATE: 1/1/2015

 

Good general ventilation should be sufficient to control airborne levels of irritating vapors. Local exhaust ventilation may be necessary for some operations.

 

Personal Protective Equipment

 

EYES: Wear safety glasses with side shields or goggles.

 

 

SKIN: Wear clean, long-sleeved, body-covering clothing. Nitrile, neoprene®, or rubber gloves should provide protection against skin contact.

 

 

INHALATION: Respiratory protection is not generally required during normal use and handling. A NIOSH/MSHA approved air purifying respirator with organic vapor cartridge or canister may be necessary under certain circumstances where airborne concentrations are expected to exceed exposure limits.

 

SECTION 8 NOTES:

 

_________________________________________________________________________________________________________________

 

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

 

Physical Properties

 

Appearance – (Color, Physical Form, Shape): Milky white liquid emulsion.

 

Odor: Slight ammonia odor.

 

Physical State: Liquid.pH: 6.0 - 9.0

 

Vapor Pressure: 17.5 mm Hg @ 68° F (20° C)

 

Vapor Density: 0.624 @ 80° F (26.7° C)

 

Boiling Point: 212° F (100° C)

 

Freezing Point: 32° F (0° C)

 

Solubility: Product as sold is dilutable. Polymer component is insoluble.

 

Specific Gravity: 0.98 - 1.04

 

 

Additional Information

 

The physical data listed are for a series of latexes. For specific properties on any given latex, see the product bulletin.

 

 

 

 

 

 

 

 

 

PAGE 6 OF 10

 

MATERIAL SAFETY DATA SHEET

FILE NO.:

HT 206

MSDS DATE: 1/1/2015

 

 

SECTION 10: STABILITY AND REACTIVITY

 

 

 

Stability

 

This material is stable during storage and during its intended use.

 

Incompatible Materials/Substances

 

Addition of chemicals, such as acids or multivalent metal salts, may cause coagulation.

 

 

 

Conditions to Avoid

 

Avoid freezing temperatures (less than 32° F or 0° C). Product can decompose at elevated temperatures.

 

 

Hazardous Decomposition Products

 

Hazardous decomposition products depend upon temperature, air supply and the presence of other materials. Thermal decomposition may produce various hydrocarbons and irritating, acrid vapors.

 

Hazardous Polymerization

 

Hazardous polymerization will not occur.

 

 

SECTION 10 NOTES:

 

 

 

SECTION 11: TOXICOLOGICAL INFORMATION

 

TOXICOLOGICAL INFORMATION:

 

 

Acute Toxicity (Humans)

 

Refer to Section 3 for available information on potential health effects.

 

 

SKIN:

 

-Based on properties of similar polymers, the polymer is not hazardous.

 

-Acrylonitrile: dermal LD50 (rabbit), 250 mg / kg.

 

INGESTION:

 

-Based on properties of similar polymers, the polymer is not hazardous.

 

-Ammonia: oral LD50 (rat), 350 mg / kg.

 

PAGE 7 OF 10

 

MATERIAL SAFETY DATA SHEET                                                                       FILE NO.:

 

HT 206                                                                                                                                                MSDS DATE: 1/1/2015

 

- Acrylonitrile: oral LD50 (rat) 36 - 85 mg / kg.

 

INHALATION:

 

-Based on properties of similar polymers, the polymer is not hazardous.

 

-Ammonia: inhalation LC50 (rat), 2,000 ppm / 4 hr.

 

-Acrylonitrile: Inhalation LC50 (rat), >1,000 ppm / 1 hr; 500 ppm / 4 hr.

 

 

SECTION 11 NOTES:

 

 

 

SECTION 12: ECOLOGICAL INFORMATION

 

ECOLOGICAL INFORMATION:

 

 

Movement & Partitioning

 

Latex dispersions will color water a milky white. No bioconcentration of the polymeric component is expected because of its high molecular weight.

 

Degradation & Persistence

 

The polymeric component is not expected to biodegrade.

 

 

Ecotoxicity

 

Based largely or completely on information for similar material(s): Material is practically non-toxic to aquatic organisms on an acute basis (LC50 or EC50 >100 mg/L in the most sensitive species tested).

 

SECTION 12 NOTES:

 

 

 

SECTION 13: DISPOSAL CONSIDERATIONS

 

WASTE DISPOSAL METHOD:

 

DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All disposal methods must be in compliance with all Federal and local laws and regulations. Waste characterizations and compliance with applicable laws are the responsibility

 

solely of the waste generator.

 

 

 

 

PAGE 8 OF 10

 

MATERIAL SAFETY DATA SHEET                                                                       FILE NO.:

 

HT 206                                                                                                                                                MSDS DATE: 1/1/2015

 

 

FOR UNUSED OR UNCONTAMINATED PRODUCT, the preferred options include sending to a licensed, permitted recycler, reclaimer,incinerator or other thermal destruction device.

 

NOT A RCRA HAZARDOUS WASTE: When discarded in its purchased form, this material would not be regulated as a RCRA Hazardous

 

waste under 40 CFR 261.

 

 

SECTION 13 NOTES:

 

 

 

SECTION 14:  TRANSPORT INFORMATION

 

Transport/further information

 

Not classified as dangerous in the meaning of transport regulations.

 

 

SECTION 14 NOTES:

 

 

 

SECTION 15: REGULATORY INFORMATION

 

U.S. Federal Regulations

 

Occupational Safety and Health Act (OSHA): This material is classified as a hazardous chemical under the criteria of the US Occupational Safety and Health Administration (OSHA) Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 8(b) - Inventory Status: All components of this material are listed on or are exempt from the US Toxic Substances Control Act (TSCA) inventory. SARA Title III Section 313 Toxic Chemical List (TCL): To the best of our knowledge, this product contains no chemical subject to SARA Title III Section 313 supplier notification requirements. SARA Hazard Category: This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories:

 

- A delayed health hazard.

 

 

Workplace Hazardous Materials Information System (WHMIS) - Canada

 

Workplace Hazardous Materials Information System (WHMIS) - Canada: This material is not classified as a controlled product under the Canadian Workplace Hazardous Material Information System. Canadian Inventory Status: All components of this material are listed on the Canadian Domestic Substances List (DSL).

 

PAGE 9 OF 10

 

MATERIAL SAFETY DATA SHEET                                                                       FILE NO.:

 

HT 206                                                                                                                                                MSDS DATE: 1/1/2015

 

 

Additional Information

 

California Proposition 65: This material contains chemicals known to the State of California to cause cancer.

 

-4-Vinylcyclohexene

 

-Acrylonitrile

 

 

INTERNATIONAL REGULATIONS:

 

 

SECTION 15 NOTES:

 

 

 

SECTION 16: OTHER INFORMATION

 

OTHER INFORMATION:

 

 

PREPARATION INFORMATION:

 

 

DISCLAIMER: This information is provided in good faith and is correct to the best knowledge of Hongtai Technology as of the date hereofand is designed to assist our customers; however, Hongtai Technology makes no representation as to its completeness or accuracy. Our products are intended for sale to industrial and commercial customers. We require customers to inspect and test our products before use and to satisfy as to suitability for their specific applications. Any use which Hongtai Technology customers or third parties make of this information, or any reliance on, or decisions made based upon it, are the responsibility of such customer or third party. Hongtai Technology disclaims responsibility for damages, or liability, of any kind resulting from the use of this information. THERE ARE NO WARRANTIES OR

REPRESENTATIONS, EXPRESS OR IMPLIED, INCLUDING THOSE OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR

 

PURPOSE WITH RESPECT TO THIS INFORMATION OR TO THE PRODUCT IT DESCRIBES.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

PAGE 10 OF 10